AN APPROACH TO THE MECHANISM OF PHOTOOXIDATION OF BERBERINE UNDER BASIC CONDITIONS
The unsensitized photooxidation of berberine (1) catalyzed by basic reagents such as -SC6H13, -N3, Et3N, -OCH3 or -OC2H5, in solution, is described.As a possible mechanism, the formation of an initial berberine-oxygen exciplex followed by a nucleophilic a
Contreras, M. Leonor,Rivas, Sergio,Rozas, Roberto
p. 101 - 106
(2007/10/02)
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