Metal-catalyzed cyclopropene rearrangements for benzannulation: Evaluation of an anthraquinone synthesis pathway and reevaluation of the parallel approach via carbene-chromium complexes
The reaction of 3-arylcyclopropenes with Cr(CO)6 and Mo(CO)6 produces naphthols, in an example of metal-promoted benzannulation. Substituents at C- 3 (in addition to aryl) have a strong effect on the success of the process: 3-H deriv
Semmelhack,Ho, Suzzy,Cohen,Steigerwald,Lee,Lee,Gilbert, Adam M.,Wutff, William D.,Ball, Richard G.
p. 7108 - 7122
(2007/10/02)
Metal Carbonyl Promoted Rearrangement of Cyclopropenes to Naphthols
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Semmelhack, M. F.,Ho, Suzzy,Steigerwald, Michael,Lee, M. C.
p. 4397 - 4399
(2007/10/02)
Ozonolysis of a Series of 1-Substituted Indenes. The Substituent Steric Effects on Ozonide Exo/Endo Ratios
The ozonolysis of a series of disubstituted (1,2 and 1,3) and trisubstituted (1,2,3) indenes 1-28 in carbon tetrachloride at 20 deg C has been investigated.The major product in each case was the corresponding bicyclic ozonide, usually obtained as a mixtur
Miura, Masahiro,Nojima, Masatomo,Kusabayashi, Shigekazu,McCullough, Kevin J.
p. 2932 - 2936
(2007/10/02)
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