Liquid crystalline and charge transport properties of novel non-peripherally octasubstituted perfluoroalkylated phthalocyanines
Two new perfluoroalkylated phthalocyanine derivatives were synthesised and characterised in order to investigate the effects of the fluorophobic/fluorophilic interactions on their mesophase and electronic properties. Both compounds exhibit columnar mesomo
PHTHALOCYANINE COMPOUND AND ORGANIC SEMICONDUCTOR MATERIAL
PROBLEM TO BE SOLVED: To provide a phthalocyanine compound having high carrier mobility or a metal complex thereof. SOLUTION: This invention relates to a compound represented by the following formula (I) or (IA) or a metal complex thereof. COPYRIGHT: (C)2
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Paragraph 0047; 0050; 0055
(2018/11/22)
New Efficient Palladium-Catalyzed Perfluoroalkylation of Carbon-Carbon Multiple Bonds with F-Alkyl Iodides. An Expedient Route to F-Alkylated Alkyl and Alkenyl Iodides
A variety of alkenes and alkynes efficiently undergo the perfluoroalkylation with F-alkyl iodides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) in hexane to give good yields of the corresponding F-alkylated alkyl and al
TRANSITION-METAL COMPLEX CATALYZED POLYFLUOROALKYLATION. I. FACILE ADDITION OF POLYFLUOROALKYL HALIDES TO CARBON-CARBON MULTIPLE BONDS
Addition of polyfluoroalkyl halides to alkynes and alkenes bearing a variety of substituents is effected by the catalysis of iron, cobalt and ruthenium carbonyl complexes to give the corresponding adducts in good to excellent yields under mild conditions.
Fuchikami, Takamasa,Ojima, Iwao
p. 303 - 306
(2007/10/02)
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