Abnormal Ring Opening of 1,2-Epoxyalkyldiphenylphosphine Oxides with Lithium Aluminum Hydride to Form 2-Hydroxyalkyldiphenylphosphine Oxides
Ring opening of 1,2-epoxyalkyldiphenylphosphine oxides with LiAlH4 gives 2-hydroxyalkyldiphenylphosphine oxides in good yield.This is the first example of ring opening of 1,2-epoxyalkyldiphenylphosphine oxides to give the corresponding 2-hydroxy derivativ
Imoto, Hiroyuki,Yamashita, Mitsuji
p. 323 - 325
(2007/10/02)
Convenient Synthesis of (1-Alkyl-2-hydroxyethyl)diphenylphosphine Oxides
(1-Alkyl-2-hydroxyethyl)diphenylphosphine oxides were synthesized from the corresponding (1-alkyl-2-oxoethyl)diphenylphosphine oxides in excellent yields.The structures of 2-hydroxy derivatives and their acetates were confirmed by elemental and spectral a