A Model for the Active Sites of Oxo-Transfer Molybdoenzymes: Synthesis, Structure, and Properties
Development of models for the active sites of oxo-transfer molybdoenzymes has been initiated.Suitable models should be capable of oxygen atom transfer to or from the substrate, approach the native coordination unit, and be inert to formation of μ-oxo Mo(V
Synthetic Approach to the Mononuclear Active Sites of Molybdoenzymes: Catalytic Oxygen Atom Transfer Reactions by Oxomolybdenum(IV,VI) Complexes with Saturation Kinetics and without Molybdenum(V) Dimer Formation
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Berg, Jeremy M.,Holm, R. H.
p. 3035 - 3036
(2007/10/02)
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