TRANSFORMATIONS OF PHENYLCYCLOPROPANES UNDER THE INFLUENCE OF VARIOUS DIACYLOXYIODO DERIVATIVES
The reaction of phenylcyclopropanes with various (diacycloxyiodo)benzenes and iodine tristrifluoracetate was studied. (Bistrichloroacetoxyiodo)benzene and (bistrifluoracetoxyiodo)benzene react with phenylcyclopropanes exclusively in the small ring with the formation of the respective 1-phenyl-1,3-bis(acyloxy)propanes.Iodine tristrifluoroacetate in reaction with phenylcyclopropanes attacks both the small ring and the aromatic ring, which leads to the production of the esters of 1,3-diols and p-iodophenylcyclopropanes.Possible mechanisms are proposed for the oxidative cleavage of the trimethyl ring of phenylcyclopropanes.
Saginova, L. G.,Bondarenko, O. B.,Gazzaeva, R. A.,Shabarov, Yu. S.
p. 477 - 480
(2007/10/02)
ACTION OF TRIFLUOROACETOXYIODO DERIVATIVES ON PHENYLCYCLOPROPANES
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Gazzaeva, R. A.,Shabarov, Yu. A.,Saginova, L. G.
p. 199 - 200
(2007/10/02)
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