Room temperature C(sp2)-H oxidative chlorination: Via photoredox catalysis
Photoredox catalysis has been developed to achieve oxidative C-H chlorination of aromatic compounds using NaCl as the chlorine source and Na2S2O8 as the oxidant. The reactions occur at room temperature and exhibit exclusive selectivity for C(sp2)-H bonds over C(sp3)-H bonds. The method has been used for the chlorination of a diverse set of substrates, including the expedited synthesis of key intermediates to bioactive compounds and a drug.
Zhang, Lei,Hu, Xile
p. 7009 - 7013
(2017/10/05)
More Articles about upstream products of 90347-04-9