Synthesis of ent-Kaurene from a Naturally Occurring Precursor
ent-Kaurene (1) has been synthesized from a naturally occurring precursor, ent-kaurane-17,19-diol (3a).Selective deoxygenation at C19 of the diol was achieved after the C17 hydroxyl was protected as the triphenylmethyl ether. ent-Kaurene was then prepared by way of an elimination sequence at C17.
Hogg, Ronald W.,Knox, John R.
p. 469 - 474
(2007/10/02)
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