Radical carbodiazenylation - A convenient and effective method to achieve carboamination of non-activated olefins
The regioselective addition of aryl and aryldiazenyl substituents to olefinic substrates can be described as carbodiazenylation. In this report we present our final results relating to this unique type of radical functionalization reaction, which has now
Blank, Olga,Wetzel, Alexander,Ullrich, Daniela,Heinrich, Markus R.
experimental part
p. 3179 - 3189
(2009/05/11)
Oxidative and reductive carbodiazenylation of nonactivated olefins
Procedures for the carbodiazenylation of nonactivated olefins with a wide range of aryldiazonium salts have been developed. The azo compounds obtained can serve as valuable precursors for /?-arylamines (carboamination products), β-amino acids, ketones, and various heterocyclic structures.
Heinrich, Markus R.,Blank, Olga,Wetzel, Alexander
p. 476 - 484
(2007/10/03)
Reductive carbodiazenylation of nonactivated olefins via aryl diazonium salts
The reduction of aryl diazonium salts in the presence of nonactivated olefins provides rapid entry to carbodiazenylation products. The regioselective functionalization of double bonds is achieved in a one-pot process starting from aniline derivatives. Car
Heinrich, Markus R.,Blank, Olga,Woelfel, Sabrina
p. 3323 - 3325
(2007/10/03)
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