- Kinetic study of charge transfer interaction between p-chloranil and aminophenols in aqueous media
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THE CHARGE-TRANSFER complexes of aminophenols (o-, m-and p-aminophenol) as donors with p-chloranil as an acceptor have been investigated by measuring visible and ultraviolet spectra in different "water-dioxane,- dimethylformamide, and-dimethylsulfoxide mixtures" at 30°C. The results revealed that the reaction follows an overall third order rate equation, through first order with respect to p-chloranil and second order with respect to the aminophenol. The rates were found to increase by increasing the dielectric constant of the medium. The reactivity of solvents and aminophenols is discussed The structure of the products was confirmed by their elemental analysis, IR, 1HNMR and mass spectroscopy.
- Abdel Sayed,El Badry
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