- Thermal Stereomutations of (2R,3R)-Phenylcyclopropane-1,2,3-2H3 and (1R,2S,3R)-Phenylcyclopropane-2-13C-1,2,3-2H3: Quantification of All Four Stereochemical Modes for Interconversions among the 1-Phenyl-1,2,3-trideuterocyclopropanes
-
Optically pure (2R,3R)-phenylcyclopropane-1,2,3-2H3 and (1R,2S,3R)-phenylcyclopropane-2-13C-1,2,3-2H3 have been prepared and the thermal stereomutations they exhibit have been followed kinetically at 309.3 deg C to provide the first complete quantificatio
- Baldwin, John E.,Barden, Timothy C.
-
-
Read Online
- Rearrangement of indene skeletons under mild conditions
-
(Chemical Equation Presented) Isomerization between two isomers of 1,2-disubstituted 3-aminoindenes occurs via the rearrangement of indene frameworks. In contrast to previous rearrangements of indene derivatives, which occur under high-temperature conditi
- Kuninobu, Yoichiro,Ueda, Hirokazu,Kawata, Atsushi,Takai, Kazuhiko
-
p. 6749 - 6752
(2008/02/11)
-
- The carbonyl group as a reluctant transmitter of hyperconjugative or ?-? spin-spin coupling interactions in derivatives of benzaldehyde, acetophenone, and benzophenone
-
Unlike their counterparts in anisole or toluene derivatives, the six-bond spin-spin coupling constants bentween para ring protons or (19)F nuclei and protons or (13)C nuclei in the sidechain of derivatives of benzaldehyde, acetophenone, and benzophenone c
- Schaeffer, Ted,Peeling, James,Penner, Glenn H.,Lemire, Alberta,Laatikainen, Reino
-
p. 1859 - 1863
(2007/10/02)
-