Orbital symmetry governed reactions under high-intensity argon laser-jet conditions: The involvement of a [1,5S] sigmatropic shift in the photocyclization of an o-alkenylbenzaldehyde to a benzocyclobutenone
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Wilson, R. Marshall,Patterson, Wesley S.,Austen, Steven C.,Ho, Douglas M.,Krause Bauer, Jeanette A.
p. 7820 - 7821
(2007/10/02)
1,7-Electrocyclisation and Carbene Reactions of o-Alkenylaryldiazoalkanes: The Effect of Alkene Configuration on the Mode of Reaction
The 1,7-8?-electron electrocyclisation of o-alkenylaryldiazoalkanes (1) to give 1H-2,3-benzodiazepines (3) takes place readily for substrates with a cis-hydrogen atom at the cyclisation site, but is blocked by phenyl or methyl groups at that position.Such
Munro, David P.,Sharp, John T.
p. 849 - 858
(2007/10/02)
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