A VINYLSILANE ROUTE TO TRANS-7a-METHYLHYDRIND-4-EN-1,6-DIONE
A stereoselective synthesis of the title compound is described.The overall yield is 34percent starting with 2-methyl-2-cyclopentenone.The trans ring-fusion stereochemistry is established by a conjugate addition/trapping sequence.
Denmark, Scott E.,Germanas, Juris P.
p. 1231 - 1234
(2007/10/02)
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