THERMAL ADDITION REACTIONS TO BENZOCYCLOBUTENONES STUDIED BY FLASH PHOTOLYSIS
Ortho-quinoid vinylketenes 2 have been generated thruogh flash photolysis of benzocyclobutenones 1.A kinetic study of intermolecular addition reactions of 2 competing with the recyclization 2 -> 1 reveals strikingly different substituent effects for the addition of methanol and of dienophiles.
Schiess, P.,Eberle, M.,Huys-Francotte, M.,Wirz, J.
p. 2201 - 2204
(2007/10/02)
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