Synthesis and solid state characterization of organometallic polymer of Ag(I) using 2,2-dimethyl-1,3-diisocyano propane ligand
2,2-Dimethyl-1,3-diisocyano propane CNCH2C(CH3J 2CH2NC was prepared and fully characterized by IR and multi-nuclear NMR spectroscopy. Treatment of CNCH2C(CH 3)2CH2NC with AgCl afforded almost quantitatively highly insoluble powder. Its X-ray powder diffractional studies revealed a polymeric structure. In this structure the Ag centres are bridged with each of the two adjacent Ag neighbours by the bidentate ligands CNCH 2(CH3)2CH2NC via the NC groups to form {Ag(CNCH2(CH3)2CH2NC)}n chains. The Cl- counterpart anions are cross linked the Ag centres of the chains to form a polymeric network {[Ag(CNCH2(CH3) 2CH2NC)]Cl}n.
Al-Ktaifani,Rukiah,Shaaban
p. 547 - 557
(2008/09/19)
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