Site-specific conversion of cysteine thiols into thiocyanate creates an IR probe for electric fields in proteins
The nitrile stretching mode of the thiocyanate moiety is a nearly ideal probe for measuring the local electric field arising from the organized environment of the interior of a protein. Nitriles were introduced into three proteins: ribonuclease S (RNase S
Fafarman, Aaron T.,Webb, Lauren J.,Chuang, Jessica I.,Boxer, Steven G.
p. 13356 - 13357
(2007/10/03)
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