A convenient preparation of di-p-chlorobenzyl azodicarboxylate (DCAD) for mitsunobu couplings
Gram-scale synthesis of pure, bench-stable solid di-p-chlorobenzyl azodicarboxylate (DCAD) is performed in two steps without resorting to chromatography. This novel reagent effects Mitsunobu couplings with yields comparable to DEAD or DIAD, while addressi
Taft, Benjamin R.,Swift, Elizabeth C.,Lipshutz, Bruce H.
experimental part
p. 332 - 334
(2009/06/18)
Simplification of the Mitsunobu reaction. Di-p-chlorobenzyl azodicarboxylate: A new azodicarboxylate
(Chemical Equation Presented) Di-p-chlorobenzyl azodicarboxylate (DCAD) is introduced as a novel, stable, solid alternative to DEAD and DIAD for a variety of Mitsunobu couplings. DCAD/Ph3P-mediated reactions in CH 2Cl2 gen
Lipshutz, Bruce H.,Chung, David W.,Rich, Brian,Corral, Ricardo
p. 5069 - 5072
(2007/10/03)
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