919102-70-8

Basic information

• Product Name: Bode Catalyst 1
• Synonyms: (5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H, 6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate;Bode Catalyst 1;[5a-S,10b-R]-2-(2,4,6-Trimethyl-phenyl)-2,5a,6,10b-tetrahydro-4H-5-oxa-2,3-diaza-10c-azonia-cyclopenta[c]fluorene chloride;(-)-(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride;(-)-(5aS,10bR)-5a,10b-Dihydro-2-mesityl-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Bode Catalyst 1;(-)-(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Monohydrate;GUECWMLEUCWYOS-OZYANKIXSA-M
• CAS NO: 919102-70-8
• Molecular Formula: C₂₁H₂₂N₃O*Cl
• Mol File: 919102-70-8.mol

Chemical Properties

• Melting Point: 212-216 °C
• Appearance: /
• Storage Temp.: Inert atmosphere,Room Temperature
• CAS DataBase Reference: Bode Catalyst 1(CAS DataBase Reference)
• NIST Chemistry Reference: Bode Catalyst 1(919102-70-8)
• EPA Substance Registry System: Bode Catalyst 1(919102-70-8)

Safety Data

• Hazardous Substances Data: 919102-70-8(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
Bode Catalyst 1 is used as an N-heterocyclic carbene (NHC) organocatalyst for various organic synthesis reactions. Its unique structure and properties make it a versatile and efficient catalyst for a range of reactions.
Used in the Synthesis of Tricyclic β-Lactones:
Bode Catalyst 1 is used as a catalyst in the synthesis of tricyclic β-lactones by reacting 2-bromoenals with 1,3-diketones. This reaction provides a convenient and efficient method for the preparation of these biologically relevant compounds.
Used in the Functionalization of the C2-Position of 3-Aminobenzofurans:
Bode Catalyst 1 is used as a catalyst in the functionalization of the C2-position of 3-aminobenzofurans using 2-bromoenals as coupling partners. This reaction allows for the selective and efficient synthesis of a variety of 3-aminobenzofuran derivatives.
Used in the Synthesis of Dihydroquinoxalines:
Bode Catalyst 1 is used as a catalyst in the synthesis of dihydroquinoxalines from substituted bisimines. This reaction provides a straightforward and efficient method for the preparation of these potentially bioactive compounds.
Used in the Preparation of Spiro-Glutarimide Derivatives:
Bode Catalyst 1 is used as a catalyst in the preparation of spiro-glutarimide derivatives by reacting cyclic β-ketoamides with α,β-unsaturated aldehydes. This reaction offers a convenient and efficient route to the synthesis of these structurally interesting and potentially bioactive compounds.

Upstream product

• 88-05-1 2,4,6-trimethylaniline 
• 862095-79-2 indeno[2,1-b]-1,4-oxazin-3(2H)-one,4,4a,9,9a-tetrahydro-,(4aR,9aS)- 
• 862095-80-5 (4aR,9aS)-3-methoxy-2,4a,9,9a-tetrahydroindeno[2,1-b][1,4]oxazine 
• 24006-09-5 mesitylhydrazine hydrochloride 
• 1345817-96-0 (Z)-2-mesityl-1-((4aR,9aS)-4,4a,9,9a-tetrahydroindeno[2,1b][1,4]oxazin-3(2H)-ylidene)hydrazine hydrochloride 
• 122-51-0 orthoformic acid triethyl ester 

Downstream Products

• 1283850-69-0 C₃₀H₂₇ClN₃O₂⁽¹⁺⁾ 

Relevant articles and documents

ENANTIOSELECTVE REACTIONS CATALYZED BY CHIRAL TRIAZOLIUM SALTS

This invention provides a convenient method for converting imines and other electrophiles into heterocyclic ring systems. The process does not require the use of metallic reagents, and is catalyzed by an organic heterocyclic carbene catalyst. Accordingly,