- Reactive dye having both monochlorotriazinyl and vinylsulfone type reactive groups
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A novel reactive monoazo dye, capable of giving cellulose fiber materials a deep orange to scarlet color and superior in build-up and chlorine fastness properties, represented by a free acid of the formula, STR1 wherein R1 is hydrogen, methyl or ethyl; R2 is an alkyl having 1 to 4 carbons that is either unsubstituted or substituted with hydroxy, cyano, alkoxy, halogen, carboxy, alkoxycarbonyl or sulfonic acid; Z is hydrogen or sulfonic acid; A is phenylene and is either unsubstituted or substituted with 1 or 2 substituents selected from the group consisting of methyl, ethyl, methoxy, ethoxy, chlorine, bromine and sulfonic acid, or natphthylene that is either unsubstituted or substituted with sulfonic acid; X is --SO2 CH=CH2 or --SO2 CH2 CH2 Y in which Y is a group that is splittable by alkalis; and m is an integer of 1 to 3.
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- Fiber reactive monoazo compounds having two vinylsulfone type fiber reactive groups in the molecule
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A monoazo compound of the following formula in a free acid form, STR1 wherein A1 and A2 are phenylene or naphthylene, Z1 and Z2 are --SO2 CH=CH2 or --SO2 CH2 CH2 Y in which Y is a splittable group, R1 and R2 are hydrogen or alkyl, and D is sulfophenyl or sulfonaphthyl, provided that --A1 --Z1 and --A2 --Z2 are different from each other when D is sulfophenyl and both R1 and R2 are hydrogen, which is useful for dyeing or printing fiber materials to give dyed products of high fastness properties with extremely high color depth.
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- Fiber-reactive disazo brown dye having vinylsulfone-type reactive group
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A compound, or a salt thereof, represented by the following formula, STR1 wherein A is a substituted or unsubstituted phenylene or naphthylene group, B is STR2 in which R3 is a hydrogen atom or a lower alkyl, lower alkoxy, acylamino or ureido group, and R4 is a hydrogen atom or a lower alkyl or lower alkoxy group, R1 and R3 are independently a hydrogen atom or a substituted or unsubstituted lower alkyl group, X is a substituted or unsubstituted amino, lower alkoxy, substituted phenoxy or sulfo group, Y is --SO2 CH=CH2 or --SO2 CH2 CH2 Z, in which Z is a group capable of being split by the action of an alkali, and m is 2 or 3, which is useful for dyeing hydroxyl group- or amide group-containing fiber materials to give dyed products of a brown color having excellent fastness properties with good build-up property.
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