The reaction of isosteric isobutyl(isopropoxy)silanes iBun(iPrO)3-nSiH (n = 0-3) with allyl bromide in the presence of platinum compounds
The isosteric silanes iBun(iPrO)3-nSiH react with allyl bromide to yield the corresponding bromides iBun(iPrO)3-nSiBr.The reactivities of the silanes fall in the sequence: iBu(iPrO)2SiH iBu2(iPrO)SiH > (iPrO)3SiH > iBu3SiH which can be accounted for in terms of the anomeric effects at the silicon atom.
Pikies, J.,Wojnowski, W.
p. 187 - 193
(2007/10/02)
More Articles about upstream products of 92731-73-2