Triquinanes from linear ketones via trimethylenemethane diyls
Linear compounds containing a ketone and diene functional groups reacted with the anion of TMS-diazomethane to produce alkylidene carbenes that underwent intramolecular cyclopropanation followed by the formation of trimethylenemethane diyls which underwent [2+3] cycloaddition reaction to produce linearly fused triquinanes.
Lee, Hee-Yoon,Kim, Won-Yeob,Lee, Sejin
p. 1407 - 1410
(2007/10/03)
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