936251-82-0

Basic information

• Product Name: methyl ({(1R)-2-{[tert-butyl(diphenyl)silyl]oxy}-1-[(phenylseleno)methyl]ethyl}oxy)acetate
• Synonyms: methyl ({(1R)-2-{[tert-butyl(diphenyl)silyl]oxy}-1-[(phenylseleno)methyl]ethyl}oxy)acetate
• CAS NO: 936251-82-0
• Molecular Weight: 541.621
• Mol File: 936251-82-0.mol

Chemical Properties

• CAS DataBase Reference: methyl ({(1R)-2-{[tert-butyl(diphenyl)silyl]oxy}-1-[(phenylseleno)methyl]ethyl}oxy)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl ({(1R)-2-{[tert-butyl(diphenyl)silyl]oxy}-1-[(phenylseleno)methyl]ethyl}oxy)acetate(936251-82-0)
• EPA Substance Registry System: methyl ({(1R)-2-{[tert-butyl(diphenyl)silyl]oxy}-1-[(phenylseleno)methyl]ethyl}oxy)acetate(936251-82-0)

Safety Data

• Hazardous Substances Data: 936251-82-0(Hazardous Substances Data)

Upstream product

• 96-32-2 bromoacetic acid methyl ester 
• 702711-07-7 (2R)-1-{[tert-butyl(diphenyl)silyl]oxy}-3-(phenylseleno)propan-2-ol 
• 744198-92-3 (2R)-3-(phenylseleno)propane-1,2-diol 
• 1666-13-3 diphenyl diselenide 

Downstream Products

• 936251-83-1 ({(1R)-2-{[tert-butyl(diphenyl)silyl]oxy}-1-[(phenylseleno)methyl]ethyl}oxy)acetaldehyde 
• 936251-85-3 (3R,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)tetrahydrofuran-3-ol 
• 936251-84-2 (3S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)tetrahydrofuran-3-ol 

Relevant articles and documents

Intramolecular addition of carbon radicals to aldehydes: synthesis of enantiopure tetrahydrofuran-3-ols

A simple and efficient substrate-controlled asymmetric synthesis of enantiopure tetrahydrofuran-3-ols by a 5-exo-trig radical cyclization is described. This cyclization occurs when a δ-carbon radical adds intramolecularly to the carbonyl group of an aldeh