A simple and efficient method for the N-nitrosation of secondary amines with NaNO2-Ac2O under mild conditions
Secondary amines can be easily converted into their corresponding nitroso derivations using NaNO2-Ac2O as a nitrosating agent in dichloromethane at room temperature with high yields.
Hou, Jian-Ye,Wang, Yu-Lu,Wang, Jin-Ye
p. 626 - 627
(2007/10/03)
A NEW RADICAL REACTION IN THE SERIES OF SCHIFF BASES. ARYLATION OF SCHIFF BASES BY NITROSOACETANILIDE
The radical arylation of schiff bases with nitrosoacetanilide was realized.The addition of the aryl radical takes place regioselectively at the imidyl carbon atom of the azomethine.
Terent'ev, A. B.,Yashkina, L. V.,Pastushenko, E. V.,Kruglov, D. E.,Safiulova, G. I.