Azolides, 7. - Phosphonate and Phosphate Group Transfer with Pyrazolides
The tert-butylammonium α-diazophosphinates 7 add onto acceptor-substituted acetylenes 8 with formation of N-phosphorylpyrazoles: Primarily formed 3H-pyrazoles 9 undergo spontaneous sigmatropic shift of the anionic PO-group to yield 10. α-Diazophosph
Regitz, Manfred,Martin, Roland
p. 1641 - 1652
(2007/10/02)
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