The studies described in this paper show that hydrocarbon oligomers are alternatives for low molecular weight alkane solvents. These oligomeric solvents are nontoxic, nonvolatile, and recyclable alternatives to heptane in thermomorphic solvent mixtures th
Harrell, Mary L.,Malinski, Thomas,Torres-López, Coralys,Gonzalez, Kimberly,Suriboot, Jakkrit,Bergbreiter, David E.
O,N-bidentate ruthenium azo complexes as catalysts for olefin isomerization reactions
A series of ruthenium complexes [(η6-p-cymene) RuCl(L)] [ligands L incorporate an azo group (1-5) or an imino group (67)] havo boon synthesized and studied as olefin isomerization catalyst with allylbenzene and 1-octene as model substrates. Temperature and catalyst/substrate mol ratio have been taken into account as parameters to optimize the isomerization reaction conditions. By using 1H, 13C NMR, FT-JR and microanalysis, the new complexes have been characterized and the molecular structure of complex 4 has been determined by crystal structure determination.
Ding, Fu,Sun, Yaguang,Verpoort, Francis
experimental part
p. 1536 - 1543
(2010/07/16)
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