Complete reductive cleavage of CO facilitated by highly electrophilic borocations
The addition of CO to [((R3N)BH2)2(μ-H)][B(C6F5)4] leads to formation of trimethylboroxine ((MeBO)3) and [(R3N)2BH2][B(C6F5
Curless, Liam D.,Clark, Ewan R.,Cid, Jessica,Del Grosso, Alessandro,Ingleson, Michael J.
supporting information
p. 10903 - 10906
(2015/06/30)
Electrophilic activation of Lewis base complexes of borane with trityl tetrakis(pentafluorophenyl)borate
Borenium ions do not accumulate under the conditions of hydride abstraction from Lewis base borane complexes (L·BH3) using trityl cation because subsequent rapid reaction with L·BH3 occurs to form B - H - B bonds. The hydride-bridged
De Vries, Timothy S.,Vedejs, Edwin
p. 3079 - 3081
(2008/10/09)
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