Conjugated nitroalkenes are readily reduced by a variety of borane and borohydride reagents. The reactions provide a convenient access to a number of nitrogen and oxygen based functional groups.
Kabalka, George W.,Laila Guindi,Varma, Rajender S.
p. 7443 - 7457
(2007/10/02)
SELECTIVE REDUCTION OF α,β-UNSATURATED NITROCOMPOUNDS WITH SODIUM BOROHYDRIDE IN METHANOLIC SOLUTIONS: A FACILE ROUTE TO NITROALKANES
α,β-Unsaturated nitroalkenes are rapidly and selectively reduced at room temperature to nitroalkanes in high yields by sodium borohydride in a tetrahydrofuran-methanol solvent system.
Varma, Rajender S.,Kabalka, George W.
p. 151 - 156
(2007/10/02)
THE REDUCTION OF α,β-UNSATURATED NITROALKENES TO NITROALKANES WITH TRIALKYLBOROHYDRIDES
α,β-Unsaturated nitroalkenes are reduced to nitronate salts by trialkylborohydrides.These salts are readily hydrolysed on silica gel to the corresponding nitroalkanes in good yields.
Varma, Rajender S.,Kabalka, George W.
p. 1093 - 1098
(2007/10/02)
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