Asymmetric hydrogenation of aromatic ketones with new P-chirogenic monophosphine ligands
Novel P-chirogenic anisylphenyl-HMOP derivatives have been synthesised from (R)-2,2′-bis-(trifluoromethanesulfonyloxy)1,1′-binaphthyl. Preliminary results concerning the asymmetric hydrogenation of acetophenone and 3,5-bis(trifluoromethyl)acetophenone with Ru(II)-HMOP complexes in combination with various diamines was also tackled.
Jahjah, Mohamad,Jahjah, Rabih,Pellet-Rostaing, Stephane,Lemaire, Marc
p. 1224 - 1232
(2008/02/05)
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