Studies toward the synthesis of pinnatoxins: the spiroimine fragment
An enantioselective approach to the spiroimine fragment of pinnatoxins is described. The strategy is based on a recently developed diastereoselective Ireland-Claisen rearrangement to establish the challenging congested quaternary and tertiary stereocenters within the cyclohexene ring.
Stivala, Craig E.,Zakarian, Armen
p. 6845 - 6848
(2008/02/13)
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