A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of Li+ ion in alkali metal batteries.
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(2008/06/13)
Triflamides for protection and cyclization of tetraamines to tetraazamacrocycles
A facile two-step synthesis of tetraazamacrocycles is reported starting from trifluoromethanesulfonyl derivatives of linear tetraamines. After cyclization, the macrocycle was deprotected using sodium in liquid ammonia.
Panetta,Yaouanc,Handel
p. 5505 - 5508
(2007/10/02)
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