REACTIONS OF METALLATED 1,3-DITHIANES WITH CARBOXYLIC ACID DERIVATIVES
2-Lithio-1,3-dithiane and 2-lithio-2-trimethylsilyl-1,3-dithiane react with nitriles to afford primary aminoketene dithioacetals in good yields; these compounds exhibit marked ambident nucleophilicity.Use of other carboxylic acid derivatives as electrophi
Page, Philip C. Bulman,van Niel, Monique B.,Westwood, Donald
p. 269 - 276
(2007/10/02)
Reaction of 1,3-Dithiane with Nitriles: Generation of Primary Aminoketene Thioacetals
The anions derived from 1,3-dithiane and 2-trimethylsilyl-1,3-dithiane react with simple nitriles to provide primary aminoketene thioacetals.
Page, Philip C. Bulman,Niel, Monique B. van,Williams, P. Howard
p. 742 - 743
(2007/10/02)
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