Palladium-Catalyzed Trimethylenemethane Reaction To Form Methylenetetrahydrofurans. Aldehyde and Ketone Substrates and the Tin Effect
The palladium-catalyzed trimethylenemethane (TMM) cycloaddition of carbonyl compounds has been shown to have a strong dependence upon the presence of cocatalysts such as tri-n-butyltin acetate, di-n-butyltin diacetate, or trimethyltin acetate.High-yieldin
Trost, Barry M.,King, Steven A.,Schmidt, Thomas
p. 5902 - 5915
(2007/10/02)
A Two Catalyst System For Cycloaddition of a Trimethylenemethane Fragment to Aldehydes
The cycloaddition of 2-trimethylsilylmethylallyl acetate to aldehydes is co-catalyzed by a Pd(0) complex and a trialkyltin acetate.
Trost, Barry M.,King, Steven A.
p. 5971 - 5974
(2007/10/02)
On the Nucleophilic Nature of a TMM-PdL2 Intermediate: A Direct Palladium-Catalyzed Addition of Trimethylenemethane to Heteroatom Unsaturation
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Trost, Barry M.,Bonk, Peter J.
p. 8277 - 8279
(2007/10/02)
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