100046-00-2

Basic information

• Product Name: Diazene, bis(2,4,6-trimethylphenyl)-, 1,2-dioxide
• CAS NO: 100046-00-2
• Molecular Formula: C18H22N2O2
• Molecular Weight: 298.385
• Mol File: 100046-00-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Diazene, bis(2,4,6-trimethylphenyl)-, 1,2-dioxide(CAS DataBase Reference)
• NIST Chemistry Reference: Diazene, bis(2,4,6-trimethylphenyl)-, 1,2-dioxide(100046-00-2)
• EPA Substance Registry System: Diazene, bis(2,4,6-trimethylphenyl)-, 1,2-dioxide(100046-00-2)

Safety Data

• Hazardous Substances Data: 100046-00-2(Hazardous Substances Data)

Upstream product

• 1196-12-9 2-nitrosomesitylene 
• 88-05-1 2,4,6-trimethylaniline 
• 1410236-31-5 [Zn(2-methyl-1-[methyl-(2-pyridin-2-yl-ethyl)amino]propane-2-thiolate)Mes] 
• 75-09-2 dichloromethane 
• 109-95-5 ethyl nitrite 

Downstream Products

• 19687-57-1 N,N'-Bis-mesityl-glyoxaldiimin-N,N'-dioxid 
• 1196-12-9 2-nitrosomesitylene 
• 19687-56-0 N-(2,4,6-Trimethylphenyl)-formaldehydnitron 

Relevant articles and documents

Reactions of organozinc thiolates with nitrosonium ion: C -nitroso formation by possible transnitrosation

The organometallic complexes [ZnPAThEt] and [ZnPAThMes], where PATh is 2-methyl-1-[methyl-(2-pyridin-2-yl-ethyl)amino]propane-2-thiolate, were prepared and their reactions with NOBF4 investigated. Formation of C-nitrosoethane and C-nitrosomesitylene, respectively, was established, and structural characterization of the latter by X-ray crystallography conclusively proved the dimeric nature of [MesNO]2 in the solid state. A transnitrosation pathway for C-nitroso formation is proposed based on theoretical calculations.