100101-46-0

Basic information

• Product Name: (1S,2R,5R,2'S)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl endo-2-bicyclo<2.2.1>heptanecarboxylate
• CAS NO: 100101-46-0
• Molecular Weight: 352.517
• Mol File: 100101-46-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1S,2R,5R,2'S)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl endo-2-bicyclo<2.2.1>heptanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R,5R,2'S)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl endo-2-bicyclo<2.2.1>heptanecarboxylate(100101-46-0)
• EPA Substance Registry System: (1S,2R,5R,2'S)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl endo-2-bicyclo<2.2.1>heptanecarboxylate(100101-46-0)

Safety Data

• Hazardous Substances Data: 100101-46-0(Hazardous Substances Data)

Upstream product

• 100101-42-6 (1S,2R,5R)-2-(1-methyl-1-phenylethyl)-5-methylcyclohexanol 
• 542-92-7 cyclopenta-1,3-diene 
• 100020-75-5 (1S,2R,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl acrylate 
• 65253-04-5 (-)-8-phenylmenthol 
• 72526-00-2 (-)-8-phenylmenthyl acrylate 

Relevant articles and documents

Mixed-Ligand Arenechromium Carbonyl Complexes as Electronic Modulators

A number of mixed ligand η6 arenechromium carbonyl complexes have been prepared and investigated for their ability to effect electronic modulation of arene chemistry. In the case of an aniline-derived system, the arenechromium carbonyl complex is able to modulate the inductive capacity of the aniline nitrogen atom and thus, regulate its anchimeric ability. In the case of 8-phenylmenthol and benzyloxazolidinone derivatives, modulation of arene π basicity is achieved, and results suggest that important vinylarene π-π interactions exist in acrylate derivatives of these chiral auxiliary systems.

A REINVESTIGATION OF ASYMMETRIC INDUCTION IN DIELS-ALDER REACTIONS

The chiral induction in the Diels-Alder addition 12, assessed reliably by (19)F-NMR-spectroscopy of the endo-esters 4, varied between 47-93 percent in favor of the 2-(R)-adducts 2 depending on the auxiliary chiral group and the Lewis-acid catalyst.