100127-88-6Relevant articles and documents
Transformation of cyclic ketimines to oxaziridines and nitrones
Voznesenskaia, Natalia G.,Shmatova, Olga I.,Nenajdenko, Valentine G.
, p. 29 - 30 (2017)
Treatment of 5-, 6- and 7-membered cyclic ketimines bearing alkyl or aryl group with m-chloroperbenzoic acid proceeds as C=N epoxidation and affords bicyclic oxaziridines in good yields, whose subsequent rearrangement gives nitrones.
Rearrangements of bicyclic nitrones to lactams: Comparison of photochemical and modified barton conditions
Zeng, Yibin,Smith, Brenton T.,Hershberger, John,Aube, Jeffrey
, p. 8065 - 8067 (2007/10/03)
The rearrangement of nitrones to lactams can be carried out by photochemical activation or by treatment with Tf2O followed by KOH-promoted rearrangement (a modification of conditions originally introduced by Barton). Substrates in which the nit