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100165-39-7

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100165-39-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 100165-39-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,0,1,6 and 5 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 100165-39:
(8*1)+(7*0)+(6*0)+(5*1)+(4*6)+(3*5)+(2*3)+(1*9)=67
67 % 10 = 7
So 100165-39-7 is a valid CAS Registry Number.

100165-39-7Downstream Products

100165-39-7Relevant articles and documents

New ferrocenyl thio- and selenoether ligands. Preparation, characterization, and their palladium(II) complexes as catalysts for selective hydrogenation and grignard cross-coupling

Honeychuck, Robert V.,Okoroafor, Michael O.,Shen, Lie-Hang,Brubaker Jr., Carl H.

, p. 482 - 490 (2008/10/08)

A number of previously unknown ferrocenyl thioethers and selenoethers, (η5-C5H5)Fe(η5-C 5H3-1-CH2NMe2-2-SR) (R = Me, Et, i-Pr, i-Bu, isopentyl, and Ph), (R,S)-(η5-C5H5)Fe(η5-C 5H3-1-CH(CH3)-NMe2-2-SR) (R = Me, Et, i-Pr, Ph, and CH2Ph), (η5-C5H5)Fe(η5-C 5H3-1-CH2NMe2-2-SeR) (R = Me, Ph, and 4-chlorophenyl), (S,R)-(η5-C5H5)Fe(η5-C 5H3-1-CH(CH3)NMe2-2-SePh), (η5-C5H4SeR)2Fe (R = Me and Ph), and (η5-C5H5)Fe(η5-C 5H4SeMe), have been made from the appropriate ferrocene precursors via lithiation and reaction with RSSR or RSeSeR. The following techniques were used for characterization: 1H and 13C NMR, IR, MS, and elemental analysis. The PdCl2 complex of (η5-C5H5)Fe(η5-C 5H3-1-CH2NMe2-2-S-i-Pr) is a selective hydrogenation catalyst under homogeneous and heterogeneous conditions for the reduction of dienes to monoenes. The PdCl2 complexes of (R,S)-(η5-C5H5)Fe(η5-C 5H3-1-CH(CH3)NMe2-2-SPh) and (S,R)-(η5-C5H5)Fe(η5-C 5H3-1-CH(CH3)NMe2-2-SePh) are effective Grignard cross-coupling agents coupling 1-chloro-1-phenylethane with allylmagnesium bromide and allylmagnesium chloride in high yield. The preparation of the PdCl2 complexes of (η5-C5H4SePh)2Fe and (η5-C5H5)Fe(η5-C 5H3-1-CH2NMe2-2-SeR) (R = Me and 4-chlorophenyl) is also described. This paper presents the first transition-metal-catalyzed Grignard cross-coupling reaction that used a ferrocenyl thioether or selenoether as a ligand.

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