100229-14-9Relevant articles and documents
Syntheses of 2,4-Dinitro-substituted Bis(phenyl)platinum(II) Compounds
Brune, Hans Albert,Stapp, Bernhard,Schmidtberg, Guenther
, p. 1845 - 1856 (2007/10/02)
Syntheses of the compounds 4-COD)(aryl)> (7b-e; 4) and cis2(aryl)> (cis-1d-f) are reported.Experiments to synthesize 4-COD> (7a) and cis-2(XC6H4)> (X = 4-CH3O; 4-CH3) (cis-1b, c) with one electron acceptor-substituted and one electron donor-substituted phenyl ring resulted in the spontaneous reductive elimination of the biphenyls 2,4-(O2N)2C6H3-C6H4X-(4) (8a-c).This observation supports the hypothesis of a donor acceptor interaction in the transition state of the reductive biphenyl elimination from cis-1.