100239-86-9

Basic information

• Product Name: 1-mesityl-4-tosylpiperazine
• Synonyms: 1-mesityl-4-tosylpiperazine
• CAS NO: 100239-86-9
• Molecular Weight: 358.505
• Mol File: 100239-86-9.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 523.9±60.0 °C(Predicted)
• Density: 1.174±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1-mesityl-4-tosylpiperazine(CAS DataBase Reference)
• NIST Chemistry Reference: 1-mesityl-4-tosylpiperazine(100239-86-9)
• EPA Substance Registry System: 1-mesityl-4-tosylpiperazine(100239-86-9)

Safety Data

• Hazardous Substances Data: 100239-86-9(Hazardous Substances Data)

Upstream product

• 88-05-1 2,4,6-trimethylaniline 
• 52601-82-8 N,N-bis(2-bromoethyl)-4-methylbenzenesulfonamide 
• 16695-22-0 N,N-bis(tosyloxyethyl)-p-toluenesulfonamide 

Downstream Products

• 91904-13-1 1-(2,4,6-trimethyl phenyl)piperazine 
• 1429754-87-9 tert-butyl 4-mesityl-6-(2-nitro-1-phenylethyl)-3,4-dihydropyrazine-1(2H)-carboxylate 
• 1121599-71-0 tert-butyl 4-mesitylpiperazine-1-carboxylate 

Relevant articles and documents

Iron-catalyzed oxidative C(3)-H functionalization of amines

Fe-catalyzed direct dehydrogenative C(3)-functionalization of tertiary arylamines was developed via activation of the sp3 C(3)-H bond. The reaction is applicable to both cyclic and acyclic amines. The key process is the catalytic desaturative enamine formation from tertiary amines and position-selective C-C bond formation (addition to nitro olefins) at the β-carbon. Products can be converted to versatile and unique nitrogen-containing molecules.