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10025-77-1

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  • FeCl3.6(H2O) Ferric chloride hexahydrate CAS 10025-77-1 Iron(III) chloride hexahydrate CAS no 10025-77-1 Iron chloride hexahydrate

    Cas No: 10025-77-1

  • USD $ 3.5-5.0 / Kiloliter

  • 5 Kiloliter

  • 3000 Metric Ton/Month

  • Chemwill Asia Co., Ltd.
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10025-77-1 Usage

Description

Ferric Chloride is the chloride of the Iron (III) form. It has various kinds of applications. In industry, it can be used in sewage treatment and drinking water production (for example, used for arsenic removal); used as a leaching agent in chloride hydrometallurgy; for etching copper in two-step redox reactions to copper (I) chloride and then to copper chloride during production of printed circuit boards; as the catalyst for the synthesis of ethylene dichloride from the reaction of ethylene with chlorine. In laboratory, it is commonly employed as a Lewis acid for catalysing reactions such as chlorination of aromatic compounds and Friedel–Crafts reaction of aromatics. The ferric chloride test can be used as a traditional colorimetric test for phenols. Ferric chloride can also be applied for the determination of total cholesterol and cholesterol esters. In disease field, it can be used to induce arterial thrombosis for thrombosis research. It can also be used for decolorization of disperse and reactive dye solutions.

Sources

https://en.wikipedia.org/wiki/Iron(III)_chloride#Uses Hering, Janet G., et al. "Arsenic removal by ferric chloride." Journal 88.4(1996):155-167. Chiamori, N, and R. J. Henry. "Study of the ferric chloride method for determination of total cholesterol and cholesterol esters. American Journal of Clinical Pathology 31.4(1959):305-309. Wang, X., and L. Xu. "An optimized murine model of ferric chloride-induced arterial thrombosis for thrombosis research. Thrombosis Research 115.2(2005):95-100. Kim, Tak Hyun, et al. "Decolorization of disperse and reactive dye solutions using ferric chloride. Desalination 161.1(2004):49-58.

Chemical Properties

Yellow/brown solid

Uses

Different sources of media describe the Uses of 10025-77-1 differently. You can refer to the following data:
1. :Iron chloride hexahydrate can be used in clinical reagents (amino acids in urine).
2. Iron(III) chloride hexahydrate is used to prepare organically templated iron phosphates. It is used for sewerage treatment of industrial wastes, chloride hydrometallurgy (Silgarin process for the production of silicon), drinking water production, production of precursors for polyvinyl chloride (PVC) and copper-based metals in printed circuit boards. It plays an important role in photoengraving and photography as an etching agent. It is useful as a mordant in dyeing and printing textiles. It is useful in the detection of phenols and phenolic derivatives; gamma-hydroxybutyric acids and also in the Trinder spot test for detecting salicylic acids.
3. Iron(III) chloride hexahydrate (FeCl3.6H2O) may be employed as an oxidant for the following conversions: Synthesis of 2-substituted 4(3H)-quinazolinones (yield = 77-93%). Oxidation of 1,4-dihydropyridines (1,4-DHPs) to corresponding pyridines. Oxidation of 4-isopropyl-1,4-DHP to dealkylated pyridine.

Application

Iron chloride hexahydrate is mainly used as water treatment agent, corrosive agent in printing plate making, electronic circuit board, chlorinating agent in metallurgical industry, oxidant and mordant in dye industry, catalyst and oxidant in organic synthesis industry, chlorinating agent, It is the raw material for the manufacture of other iron salts and pigments and used in mine beneficiation. It is used as a flocculant in the purification of drinking water and industrial water supply. It has good solubility and excellent flocculation effect. Can be used for activated sludge dewatering. The pH range used is 6 to 11, and the optimum pH range is 6 to 8.4. The usual dosage is 5-100 mg/L. The flocs formed are coarse, the sedimentation speed is fast, and it is not affected by temperature. It is used to treat wastewater with high turbidity, and the effect is more significant. The corrosiveness of Iron chloride hexahydrate is stronger than that of ferrous sulfate, and the dosing equipment needs to be treated with anticorrosion. When it dissolves in water, it produces hydrogen chloride gas, which pollutes the surrounding environment. In addition, Iron chloride hexahydrate can also be used as a waterproofing agent, a corrosive agent for printing and plate making, an oxidant and mordant in the dye industry, a catalyst for organic synthesis, and the manufacture of other iron salts. It can be used as etchant, catalyst, mordant, oxidant, chlorinating agent, condensing agent, disinfectant, hemostatic agent, feed additive, water purifying agent and analytical reagent, etc. Iron chloride hexahydrate is used in nutritional supplements (iron fortifiers). For infant milk powder, weaning food, etc.

Definition

ChEBI: A hydrate that is the hexahydrate form of iron trichloride.

General Description

The iron catalysts are known to be inexpensive and environmentally benign.

Purification Methods

An aqueous solution, saturated with the salt at room temperature, is cooled to -20o for several hours. Separation of the crystals is slow, even with scratching and seeding, and it is generally necessary to stir this overnight. The presence of free HCl retards crystallisation. [Linke J Phys Chem 60 91 1956].

Check Digit Verification of cas no

The CAS Registry Mumber 10025-77-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,0,2 and 5 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 10025-77:
(7*1)+(6*0)+(5*0)+(4*2)+(3*5)+(2*7)+(1*7)=51
51 % 10 = 1
So 10025-77-1 is a valid CAS Registry Number.
InChI:InChI=1/3ClH.Fe.6H2O/h3*1H;;6*1H2/q;;;+2;;;;;;/p-3

10025-77-1 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (12497)  Iron(III) chloride hexahydrate, ACS, 97.0-102.0%   

  • 10025-77-1

  • 25g

  • 220.0CNY

  • Detail
  • Alfa Aesar

  • (12497)  Iron(III) chloride hexahydrate, ACS, 97.0-102.0%   

  • 10025-77-1

  • 250g

  • 363.0CNY

  • Detail
  • Alfa Aesar

  • (12497)  Iron(III) chloride hexahydrate, ACS, 97.0-102.0%   

  • 10025-77-1

  • 1kg

  • 1164.0CNY

  • Detail
  • Alfa Aesar

  • (12497)  Iron(III) chloride hexahydrate, ACS, 97.0-102.0%   

  • 10025-77-1

  • 5kg

  • 2488.0CNY

  • Detail
  • Alfa Aesar

  • (A16231)  Iron(III) chloride hexahydrate, 97%   

  • 10025-77-1

  • 500g

  • 311.0CNY

  • Detail
  • Alfa Aesar

  • (A16231)  Iron(III) chloride hexahydrate, 97%   

  • 10025-77-1

  • 2500g

  • 899.0CNY

  • Detail
  • Alfa Aesar

  • (A16231)  Iron(III) chloride hexahydrate, 97%   

  • 10025-77-1

  • 10000g

  • 1779.0CNY

  • Detail
  • Sigma-Aldrich

  • (236489)  Iron(III)chloridehexahydrate  ACS reagent, 97%

  • 10025-77-1

  • 236489-5G

  • 417.69CNY

  • Detail
  • Sigma-Aldrich

  • (236489)  Iron(III)chloridehexahydrate  ACS reagent, 97%

  • 10025-77-1

  • 236489-100G

  • 703.17CNY

  • Detail
  • Sigma-Aldrich

  • (236489)  Iron(III)chloridehexahydrate  ACS reagent, 97%

  • 10025-77-1

  • 236489-500G

  • 1,130.22CNY

  • Detail
  • Sigma-Aldrich

  • (236489)  Iron(III)chloridehexahydrate  ACS reagent, 97%

  • 10025-77-1

  • 236489-6X500G

  • 5,028.66CNY

  • Detail
  • Sigma-Aldrich

  • (F2877)  Iron(III)chloridehexahydrate  reagent grade, ≥98%, chunks

  • 10025-77-1

  • F2877-100G

  • 304.20CNY

  • Detail

10025-77-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name iron trichloride hexahydrate

1.2 Other means of identification

Product number -
Other names Ferric chloride hexahydrate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10025-77-1 SDS

10025-77-1Relevant articles and documents

Complexes of iron(III) with 1,2-dihydro-1,5-dimethyl-2-phenyl-4- formyl(benzhydrazide)-3H-pyrazol-3-one

Radhakrishnan,Raju

, p. 1812 - 1816 (2007/10/03)

Iron(III) complexes of the schiff base, 1,2-dihydro-1,5-dimethyl -2- phenyl -4- formyl(benzhydrazide)-3H-pyrazol-3-one, [Fe(DPFBP)2X]X 2, (where X=ClO4, or NO3) and [Fe(DPFBP) 2X2]X (X=SCN,

Synthesis and thermal studies on iron(III) complexes of 4-N-(4′-antipyrylmethylidene)aminoantipyrine with varying counter ions

Madhu,Radhakrishnan,Grunert, Matthias,Weinberger, Peter,Linert, Wolfgang

, p. 73 - 84 (2008/10/08)

Iron(III) complexes of the Schiff base 4-N-(4′ -antipyrylmethylidene)aminoantipyrine (AA) with counter ions, such as, perchlorate, nitrate, thiocyanate, chloride and bromide have been prepared and characterized by elemental analyses, electrical conductance in non-aqueous solvents, IR and electronic spectra, magnetic susceptibility measurements as well as by thermogravimetric analysis. The complexes have the general formulae [Fe(AA)2(CO4)](ClO4)2, [Fe(AA)2X2]X (X = NO3- or Br-) and [Fe(AA)X3] (X = SCN- or Cl-). In complexes, AA acts as a neutral bidentate ligand, coordinating through one of the carbonyl oxygens and azomethine nitrogen in perchlorate, nitrate and bromide complexes while the coordination of AA occurs in a neutral tridentate fashion through both carbonyl oxygens and azomethine nitrogen in thiocyanate and chloride complexes. In the perchlorate complex, one of the perchlorate ions is coordinated bidentately while in the nitrate complex two of the nitrate ions are coordinated monodentately to the metal ion. In the thiocyanate and chloride complexes all the anions are coordinated while in the bromide complex two of the bromide ions are coordinated. A high spin octahedral geometry is assigned to the iron(III) ion in all these complexes. The phenomenological, kinetic and mechanistic aspects of the nitrate, thiocyanate, chloride and bromide complexes were studied by TG and DTG techniques. The kinetic parameters like activation energy, pre-exponential factor and entropy of activation were also computed. The rate controlling process in all stages of decomposition is random nucleation with one on each particle (Mampel model) [Thermochim. Acta 2 (1971) 423].

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