10027-79-9Relevant articles and documents
An improved procedure for the conversion of alkenes and glycals to 1,2- diazides using Mn(OAc)3·2H2O in acetonitrile containing trifluoroacetic acid
Snider, Barry B.,Lin, Hong
, p. 1913 - 1922 (1998)
Alkenes and Glycals react with Mn(OAc3)·2H2O and NaN3 in 9:1 acetonitrile-trifluoroacetic acid to give 1,2-diazides in >80% yield. Allylic azides are formed by slow addition of NaN3 to a mixture of alkene, Mn(OA
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Swift,G.,Swern,D.
, p. 511 - 517 (1967)
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One-Pot and Stereospecific Synthesis of cis-1,2-Diazides via Mitsunobu Reaction of Epoxides
Goeksu, Sueleyman,Secen, Hasan,Suetbeyaz, Yasar
, p. 2373 - 2378 (2007/10/03)
Mitsunobu reaction of epoxides using hydrazoic acid, diethylazodicarboxylate, and triphenylphosphine as reagents gave the corresponding cis-1,2-diazides in moderate yield. Application of similar reaction conditions to trans-diols furnished the corresponding trans-1,2-diazides.
New Trialkylsilyl Enol Ether Chemistry: Direct 1,2-Bis-azidonation of Triisopropylsilyl Enol Ethers: an Azido-radical Addition Process Promoted by TEMPO
Magnus, Philip,Roe, Michael B.,Hulme, Christopher
, p. 263 - 266 (2007/10/02)
Treatment of triisopropylsilyl enol ethers with PhIO/TMSN3/TEMPO(cat.) -45 deg C results in 1,2-bis-azidonation, which appears to occur through a radical addition process; the 1-azido group can be replaced by carbon nucleophiles such as allyl,
