100281-30-9Relevant articles and documents
Reaction of lithium (2,4,6-tri-tert-butylphenyl)silylphosphides with haloforms
Sasaki, Shigeru,Yoshifuji, Masaaki,Inamoto, Naoki
experimental part, p. 15 - 23 (2012/03/08)
The reaction of lithium (tert-butyldimethylsilyl)(2,4,6-tri-tert- butylphenyl)phosphide with chloroform afforded (Z)-2-(tert-butyldimethylsilyl)- 2-chloro-1-(2,4,6-tri-tert-butylphenyl)-1- phosphaethene. The NMR study revealed a secondary phosphine result
Phosphinidene transfer reactions of the terminal phosphinidene complex Cp2Zr(PC6H2-2,4,6-t-Bu3)(PMe 3)
Breen, Tricia L.,Stephan, Douglas W.
, p. 11914 - 11921 (2007/10/03)
The terminal zirconium phosphinidene complex Cp2Zr(PR*)(PMe3) (R* = C6H2-2,4,6-t-Bu3) 2 has been synthesized in high yield, and its reactivity has been investigated. The compound Cp2ZrMe(PH
A New Preparative Route to Phosphaethynes from Dichlorophosphaethenes by Lithiation, Photoisomerization, and Re-lithiation Involving Migration
Yoshifuji, Masaaki,Kawanami, Hajime,Kawai, Yoshinori,Toyota, Kozo,Yasunami, Masafumi,et al.
, p. 1053 - 1056 (2007/10/02)
2-(2,4,6-Tri-t-butylphenyl)-1-phosphaethyne was prepared from 2,2-dichloro-1-(2,4,6-tri-t-butylphenyl)-1-phosphaethene by lithiation of anti-chloro atom followed by hydrolysis, photoisomerization, and repeated lithiation involving migration.The present me