100330-67-4

Basic information

• Product Name: N'-(4-Methoxy-phenyl)-N,N-dimethyl-2-oxo-2-phenyl-acetamidine
• Synonyms: N'-(4-Methoxy-phenyl)-N,N-dimethyl-2-oxo-2-phenyl-acetamidine
• CAS NO: 100330-67-4
• Molecular Weight: 282.342
• Mol File: 100330-67-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N'-(4-Methoxy-phenyl)-N,N-dimethyl-2-oxo-2-phenyl-acetamidine(CAS DataBase Reference)
• NIST Chemistry Reference: N'-(4-Methoxy-phenyl)-N,N-dimethyl-2-oxo-2-phenyl-acetamidine(100330-67-4)
• EPA Substance Registry System: N'-(4-Methoxy-phenyl)-N,N-dimethyl-2-oxo-2-phenyl-acetamidine(100330-67-4)

Safety Data

• Hazardous Substances Data: 100330-67-4(Hazardous Substances Data)

Upstream product

• 1516-21-8 4-methoxynitrosobenzene 
• 14548-16-4 Dimethyl-(1-phenyl-vinyl)-amine 

Downstream Products

• 39164-99-3 N-(4-methoxyphenyl)-2-oxo-2-phenylacetamide 

Relevant articles and documents

New rearrangement in the reaction of 1-aryl-1-(dimethylamino)-ethylenes with nitrosobenzenes. Molecular and crystal structure of N1,N1-dimethyl-N2-phenyl-2-oxo(3-pyridyl)acetamidine

The reaction of aryleneamines Ar(NMe2)C=CH2 (Ar= Ph, 2-Py, 3-Py, 4-Py) with nitrosobenzenes p-RC6H4NO (R= H, Cl, Br, Me, MeO) in benzene or ether (20 deg C) is accompanied by rearrangement and leads to N1,N1-dimethyl-N2-aryl-2-oxo(aryl)-acetamidines (20-40percent) and a mixture of products from reduction of the nitroso compounds.The effect of temperature on the yield of the amidines is insignificant, and the presence of one or two methyl groups at the β position of the enamine leads to the formation of only azoxybenzene.Accepting substituents in the nitrosobenzenes do not affect the yield of the rearrangement products, while donors reduce it.The reaction is accompanied by the formation of radical particles, and a reaction scheme is proposed.The acid hydrolysis of the obtained amidines and their reduction with lithium aluminum hydride were investigated.