100337-63-1

Basic information

• Product Name: Benzene, 1-methyl-2-(1-phenyl-1-propenyl)-
• CAS NO: 100337-63-1
• Molecular Formula: C16H16
• Molecular Weight: 208.303
• Mol File: 100337-63-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-2-(1-phenyl-1-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-2-(1-phenyl-1-propenyl)-(100337-63-1)
• EPA Substance Registry System: Benzene, 1-methyl-2-(1-phenyl-1-propenyl)-(100337-63-1)

Safety Data

• Hazardous Substances Data: 100337-63-1(Hazardous Substances Data)

Upstream product

• 932-31-0 ortho-tolylmagnesium bromide 
• 873-66-5 1-propenylbenzene 
• 673-32-5 1-Phenylprop-1-yne 
• 108-88-3 toluene 
• 82357-52-6 1-((Z)-2-Bromo-1-phenyl-propenyl)-2-methyl-benzene 

Relevant articles and documents

Pd-Catalyzed Oxidative Heck Reaction of Grignard Reagents with Diaziridinone as Oxidant

A novel Pd-catalyzed oxidative Heck reaction with readily available Grignard reagents using di-t-butyldiaziridinone as an oxidant has been developed. Various substituted olefins were obtained in 46-91% yields with high regioselectivity under mild reaction conditions.

A NOVEL ORTHO-SUBSTITUENT EFFECT ON FORMATION OF VINYL CATIONS IN THE PHOTOLYSIS OF VINYL BROMIDES

Introduction of a substituent into ortho-position of β-aryl group in a vinyl bromide resulted in the preferential formation of a vinyl cation in the photolysis.It is considered that the steric repulsion of β-aryl groups makes a convenient conformation for an electron transfer from the aromatic ring to the halogen atom in the radical pair.