10035-06-0

Basic information

• Product Name: Bismuth nitrate pentahydrate
• Synonyms: Bismuth(III) trisnitrate·pentahydrate;Bismuth(III) nitrate pentahydrate, ACS grade;Bismuth(III) nitrate pentahydrate, (trace metal basis), 99.999%;BisMuth(III) nitrate pentahydrate, 99.999%, (trace Metal basis);BisMuth(III) nitrate pentahydrate, 99.999% 25GR;BisMuth(III) nitrate pentahydrate, ACS reagent;Bismuth(Ⅲ) nitrate pentahydrate;BisMuth(III) nitrate pentahydrate >=99.99% trace Metals basis
• CAS NO: 10035-06-0
• Molecular Formula: BiH10N3O14
• Molecular Weight: 485.07
• EINECS: 233-791-8
• Product Categories: metal nitrate salts;Bismuth Salts;Catalysis and Inorganic Chemistry;Chemical Synthesis;Materials Science;Metal and Ceramic Science;Bismuth Salts;BismuthMetal and Ceramic Science;Salts;ACS GradeChemical Synthesis;Essential Chemicals;Routine Reagents;Bismuth;Catalysis and Inorganic Chemistry;Chemical Synthesis
• Mol File: 10035-06-0.mol

Chemical Properties

• Melting Point: 30 °C(lit.)
• Boiling Point: 75-80 °C(lit.)
• Appearance: White/Solid
• Density: 2,83 g/cm3
• Solubility: Soluble in dilute nitric acid solution, dilute acetic acid, glyc
• Water Solubility: MAY DECOMPOSE
• Sensitive: Hygroscopic
• Stability: Stable. Incompatible with strong acids, strong reducing agents, organic materials, finely powdered metals, moisture. Strong oxid
• Merck: 14,1271
• CAS DataBase Reference: Bismuth nitrate pentahydrate(CAS DataBase Reference)
• NIST Chemistry Reference: Bismuth nitrate pentahydrate(10035-06-0)
• EPA Substance Registry System: Bismuth nitrate pentahydrate(10035-06-0)

Safety Data

• Hazard Codes: O,Xi
• Statements: 8-36/37/38
• Safety Statements: 17-26-36-37/39
• RIDADR: UN 1477 5.1/PG 2
• WGK Germany: 2
• RTECS: EB2984430
• F: 8
• TSCA: Yes
• HazardClass: 5.1
• PackingGroup: II
• Hazardous Substances Data: 10035-06-0(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
Bismuth nitrate pentahydrate is used as a reagent for a variety of applications in organic synthesis, including the conversion of thiocarbonyls to their carbonyl compounds and the oxidative deprotection of dithioacetals.
Used in Pharmaceutical Industry:
Bismuth nitrate pentahydrate is used as a catalyst in the chemo-selective synthesis of acylals from aromatic aldehydes, one-pot synthesis of alpha-amino phosphates, and pharmaceutically functionalized piperidine derivatives.
Used in Cosmetics, Batteries, Paints, and Pigment Plastics Manufacturing:
Bismuth nitrate pentahydrate is used as an additive in the manufacturing of cosmetics, batteries, paints, and pigment plastics.
Used in Photocatalyst Preparation:
Bismuth nitrate pentahydrate acts as a precursor in the preparation of photocatalysts.
Used in Luminous Paints and Bismuth Salts Preparation:
Bismuth nitrate pentahydrate is used in the preparation of luminous paints and bismuth salts.
Used as an Oxidant:
Bismuth nitrate pentahydrate is an excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines and serves as a reagent for selective oxidation of sulfides to sulfoxides.
Used in the Preparation of Dragendorff Reagent and as a TLC Stain:
Bismuth nitrate pentahydrate is involved in the preparation of Dragendorff reagent and is used as a thin-layer chromatography (TLC) stain.
Physical Properties:
Bismuth nitrate pentahydrate is characterized by its lustrous triclinic crystals, acid taste, hygroscopic nature, density of 2.83 g/cm3, decomposition at 75°C, slow reaction with water, solubility in acids and acetone, and insolubility in alcohol.
Chemical Properties:
Bismuth nitrate pentahydrate is a white crystalline compound with various applications in different industries, making it a versatile and valuable reagent in organic synthesis and other fields.

Chemical Synthesis

Bismuth(III) nitrate pentahydrate may be used in the following processes: Conversion of thioamides and thioureas to their oxo derivatives. Transformation of aromatic aldehydes to carboxylic acids under microwave and solvent free conditions. Synthesize coumarins by Pechmann condensation under solvent free conditions. As a precursor in the synthesis of pure and lanthanum-modified bismuth ferrite (BFO) ceramics. As a nitrating agent in the synthesis of methyl nitramino-2,4,6-trinitrobenzenes under microwave irradiation. As a catalyst in the preparation of 4-amino-5-pyrimidine carbonitrile and pyrimidinone derivatives. Synthesis of glycosides by Fischer glycosylation of unprotected sugars. Synthesis of bismuth oxide (Bi2O3) nanoparticles. Oxidation of 4-substituted Hantzsch 1,4-dihydropyridines. Selective oxidation of sufides to sulfoxides.

Preparation

Bismuth nitrate pentahydrate can be obtained by dissolving metallic bismuth granules in nitric acid, or by pouring molten metallic bismuth into an acid solution while stirring.

Preparation

Bismuth nitrate is prepared by dissolving bismuth in concentrated nitric acid, followed by evaporation and crystallization .

Sources

https://en.wikipedia.org/wiki/Bismuth(III)_nitrate Bhattacharya, Asish K., and T. Kaur. ?Cheminform 38.30(2007):0745-0748. Aggen, David H., et al. Tetrahedron 35.31(2004):3675-3679. Brahmachari, Goutam, and S. Das. Cheminform 43.28(2012):1479-1484. Srivastava, Neeta, S. K. Dasgupta, and B. K. Banik. Tetrahedron Letters 34.17(2003):1191-1193. Banik, Bimal K., I. Garcia, and F. R. Morales. Cheminform 38.33(2007):no-no. Srivastava, N, and B. K. Banik. Cheminform 68.6(2003):2109-14. https://www.sigmaaldrich.com/catalog/product/aldrich/254150?lang=en®ion=US https://www.webmd.com/vitamins/ai/ingredientmono-1502/bismuth

InChI:InChI=1/Bi.NO3.5H2O/c;2-1(3)4;;;;;/h;;5*1H2/q+3;-1;;;;;