100363-25-5Relevant articles and documents
Electroreduction of Organic Compounds, 6. Electroreduction of N,N-Disubstituted Thioamides in the Presence of Electrophils
Voss, Juergen,Wiegand, Gabriele,Huelsmeyer, Karin
, p. 4806 - 4820 (2007/10/02)
Electron-uptake by the N,N-disubstituted thioamides 1-4 in aprotic medium and the behaviour of their radical anions depend substantially on the nature of the thioacyl group and the nitrogen substituents as shown by polarographic and cyclovoltammetric measurements. - Good yields of the α-amino thioethers 8-13 are obtained by preparative electroreduction in the presence of alkylating agents.The corresponding α-amino-silyl thioethers 23 are further reduced to α-(trimethylsilyl)benzylamines 24.In the presence of oxygen and ethyl halide S-ethyl thiobenzoate (27) is formed from 2a or c.