100366-06-1 Usage
General Description
(1,5-Cyclooctadiene)[(3R,4R)-3,4-bis(diphenylphosphino)-1-methylpyrrolidine]rhodium Tetrafluoroborate is a chemical compound commonly used in organic synthesis and catalysis. It is a complex of rhodium with a chiral bisphosphine ligand and 1,5-cyclooctadiene as a supporting ligand. This complex is often used as a catalyst in various organic reactions, such as hydrogenation, hydrosilylation, and carbon-heteroatom bond formation. The presence of the chiral ligand in this complex allows for enantioselective transformations, making it a valuable tool in asymmetric synthesis. The tetrafluoroborate anion helps to stabilize the rhodium center and provides counter ions for the complex. Overall, this compound plays a crucial role in the development of efficient and selective methods for the synthesis of complex molecules.
Check Digit Verification of cas no
The CAS Registry Mumber 100366-06-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,0,3,6 and 6 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 100366-06:
(8*1)+(7*0)+(6*0)+(5*3)+(4*6)+(3*6)+(2*0)+(1*6)=71
71 % 10 = 1
So 100366-06-1 is a valid CAS Registry Number.
100366-06-1Relevant articles and documents
Enantioselective Catalytic Hydrogenation of α-(Acetylamino)cinnamic Acid with a Rhodium Phosphane Complex in Aqueous Solution
Nagel, Ulrich,Kinzel, Elke
, p. 1731 - 1733 (2007/10/02)
The synthesis of (1,5-cyclooctadiene)rhodium bis(tetrafluoroborate) (5) is described.With this water-soluble catalyst the sodium salt 6c of α-(Acetylamino)cinnamic acid (6a) is hydrogenated in aqueous solution to give (S)-N-acetylphenylalanine with 90percent ee.
