100397-81-7

Basic information

• Product Name: Benzene, 1-bromo-4-[[(4-chlorophenyl)sulfinyl]methyl]-
• CAS NO: 100397-81-7
• Molecular Formula: C13H10BrClOS
• Molecular Weight: 329.645
• Mol File: 100397-81-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-bromo-4-[[(4-chlorophenyl)sulfinyl]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-4-[[(4-chlorophenyl)sulfinyl]methyl]-(100397-81-7)
• EPA Substance Registry System: Benzene, 1-bromo-4-[[(4-chlorophenyl)sulfinyl]methyl]-(100397-81-7)

Safety Data

• Hazardous Substances Data: 100397-81-7(Hazardous Substances Data)

Upstream product

• 100397-85-1 (4-bromobenzyl)(4-chlorophenyl)sulfane 

Relevant articles and documents

Selective oxidation of sulfides to sulfoxides and sulfones using hydrogen peroxide (H2O2) in the presence of zirconium tetrachloride

Hydrogen peroxide (H2O2) in the presence of zirconium tetrachloride is a very efficient reagent for the oxidation of sulfides to sulfoxides and sulfones in methanol at room temperature. It is noteworthy that under such conditions, the sulfide function is highly reactive, and various other functional groups such as alkenes and a ketone are tolerated.

Selective oxidation of sulfides to sulfoxides and sulfones using n-butyltriphenylphosphonium dichromate (BunPPh3) 2Cr2O7 in the presence of aluminium chloride in solution and under microwave irradiation

A wide variety of sulfides are efficiently oxidized to their corresponding sulfoxides and sulfones in excellent yields using n-butyltriphenylphosphonium dichromate (BTPPDC) in the presence of aluminium chloride in acetonitrile solution and under microwave irradiation. In addition, selective oxidation of sulfides in the presence of functional groups such as a carbon-carbon double bond, ketone, oxime, aldehyde, ether, and acetal can be considered as a noteworthy advantage of this method. Copyright Taylor & Francis Inc.