100397-85-1

Basic information

• Product Name: Benzene, 1-bromo-4-[[(4-chlorophenyl)thio]methyl]-
• CAS NO: 100397-85-1
• Molecular Formula: C13H10BrClS
• Molecular Weight: 313.645
• Mol File: 100397-85-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-bromo-4-[[(4-chlorophenyl)thio]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-4-[[(4-chlorophenyl)thio]methyl]-(100397-85-1)
• EPA Substance Registry System: Benzene, 1-bromo-4-[[(4-chlorophenyl)thio]methyl]-(100397-85-1)

Safety Data

• Hazardous Substances Data: 100397-85-1(Hazardous Substances Data)

Upstream product

• 106-38-7 para-bromotoluene 
• 106-54-7 p-Chlorothiophenol 
• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 589-15-1 1-bromomethyl-4-bromobenzene 
• 18803-44-6 sodium p-chlorothiophenolate 

Downstream Products

• 100397-81-7 4-bromobenzyl 4-chlorophenyl sulfoxide 
• 100397-83-9 4-bromobenzyl 4-chlorophenyl sulfone 

Relevant articles and documents

Selective approach to thioesters and thioethers via sp3 C-H activation of methylarenes

Novel C-S cross-dehydrogenative coupling (CDC) approaches for the selective synthesis of thioesters and thioethers have been developed via sp3 C-H activation of methylarenes and subsequent functionalization. The reaction of methylarenes with thiols resulted in thioesters in the presence of a FeBr2/TBHP system, while treatment of methylarenes with thiols in the Pd(OAc)2/O2/TBHP system led to the formation of thioethers. Both the green protocols demonstrate good functional group tolerance and satisfactory yields. This journal is