100422-00-2

Basic information

• Product Name: (1R,4R,6S)-5,5,6-Trimethyl-1,4-diphenyl-2,3,7-trioxa-bicyclo[2.2.1]heptane
• CAS NO: 100422-00-2
• Molecular Weight: 296.366
• Mol File: 100422-00-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,4R,6S)-5,5,6-Trimethyl-1,4-diphenyl-2,3,7-trioxa-bicyclo[2.2.1]heptane(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4R,6S)-5,5,6-Trimethyl-1,4-diphenyl-2,3,7-trioxa-bicyclo[2.2.1]heptane(100422-00-2)
• EPA Substance Registry System: (1R,4R,6S)-5,5,6-Trimethyl-1,4-diphenyl-2,3,7-trioxa-bicyclo[2.2.1]heptane(100422-00-2)

Safety Data

• Hazardous Substances Data: 100422-00-2(Hazardous Substances Data)

Upstream product

• 87894-19-7 1,2-diphenyl-3,3,4-trimethylcyclobutene 

Downstream Products

• 100422-01-3 2,3-dibenzoyl-2-methylbutane 

Relevant articles and documents

THE SENSITIZED PHOTOOXYGENATION OF METHYL SUBSTITUTED 1,2-DIPHENYLCYCLOBUTENES

A series of Me substituted 1,2-diphenylcyclobutenes was subjected to dye-sensitized photooxidation in the presence of methylene blue.In the case of the 3,3-dimethyl-, 3,3,4-trimethyl- and 3,3,4,4-tetramethyl-1,2-diphenylcyclobutenes, the sensitized oxidations are accompanied by ring-contraction with concomitant ortho hydroxylation of one aromatic nucleus.When electron transfer induced photooxidation techniques utilizing 9,10-dicyanoanthracene (DCA) as a sensitizer are employed with the series of Me substituted diphenylcyclobutenes, the reactions take a markedly different course and a broad spectrum of oxidation products are obtained including, most notably, ozonides of the cyclobutenes.The mechanisms of these conversions are addressed and the significance of the results discussed.