100422-07-9

Basic information

• Product Name: 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate
• Synonyms: 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate
• CAS NO: 100422-07-9
• Molecular Weight: 436.114
• Mol File: 100422-07-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate(100422-07-9)
• EPA Substance Registry System: 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate(100422-07-9)

Safety Data

• Hazardous Substances Data: 100422-07-9(Hazardous Substances Data)

Upstream product

• 1493-13-6 trifluorormethanesulfonic acid 
• 100422-04-6 (2,2,2-trifluoroethyl)-λ³-iodanediyl bis(2,2,2-trifluoroacetate) 
• 71-43-2 benzene 
• 768-32-1 trimethylphenylsilane 
• 166903-48-6 1-iodo>-1H,1H-perfluoroethane 

Downstream Products

• 351-61-1 N-(2,2,2-trifluoroethyl)-aniline 
• 21249-93-4 (2,2,2-trifluoroethyl)benzene 
• 92-94-4 [1,1';4',1'']terphenyl 
• 84-15-1 o-terphenyl 
• 34883-41-5 3,5-dichlorobiphenyl 
• 720-75-2 methyl 4-phenylbenzoate 
• 2920-38-9 4-cyano-1,1'-biphenyl 
• 70253-78-0 2,2,2-trifluoroethyl dodecanoate 
• 1431135-22-6 C₃₁H₃₃F₆N₇O₉ 
• 135654-55-6 2,2,2-trifluoroethyltriphenylphosphonium trifluoromethanesulfonate 
• 104207-52-5 N,N-Dimethyl-N-(2,2,2-trifluoroethyl)anilinium triflate 
• 135654-49-8 diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate 
• 106241-25-2 Benzyldimethyl(2,2,2-trifluoroethyl)ammonium triflate 

Relevant articles and documents

1-[Hydroxy(sulfonyloxy)iodo]-2,2,2-trifluoroethanes, CF3CH2I(OH)OSO2R: Stable, fluoroalkyl analogs of Koser's reagent

1-[Hydroxy(sulfonyloxy)iodo]-2,2,2-trifluoroethanes [CF3CH2I(OH)OSO2R; R = CH3, CF3, p-CH3C6H4] can be prepared in two steps from trifluoroethyliodide by oxidation with pertrifluoroacetic acid and subsequent reaction with TsOH, MsOH, or Me3SiOTf. Reaction of the tosylate derivative 3 with silyl enol ethers affords α-tosyloxyketones, while triflate 5 smoothly reacts with trimethylsilylbenzene to give the respective trifluoroethyl(phenyl)iodonium triflate 8.

Fluoroalkylaryliodonuim compounds

Fluoroalkylaryliodonium compounds having the formula (I): STR1 wherein AR, A and Rf are as defined above, are disclosed. The fluoroalkylaryliodonium compounds of the present invention are useful as intermediates for producing N-fluoroalkylanilines or deri